Adams decarboxylation

Adams decarboxylation jẹ́ ìdàpọ̀ ṣiṣẹ́ kẹ́míkà tí ó ní ṣe pẹ̀lú yíyọ ẹgbẹ́ carbonyl kúrò nínú coumarins tí ó ní ẹgbẹ́ carboxylic acid ní ipò kjẹta. A maa ń ṣe íyọ ẹgbẹ́ carbonyl kúrò yìuí kúrò nípasẹ àpòpọ̀ aqueous ti sodium bisulfite, ooru àti àpòpọ̀ líle ti sodium hydroxide.^[1]^[2]^[3]

Àwọn ìtọ́kasí àtúnṣe

↑ Adams, R.; Mathieu, J. (1948). "A New Synthesis of Atranol (2,6-Dihydroxy-4-methylbenzaldehyde) and the Corresponding Cinnamic Acid". J. Amer. Chem. Soc. 70 (6): 2120. doi:10.1021/ja01186a037.
↑ Adams, R.; Bockstaheler, T.E. (1952). "Preparation and Reactions of o-Hydroxycinnamic Acids and Esters". J. Amer. Chem. Soc. 74 (21): 5346. doi:10.1021/ja01141a038.
↑ Cramer, F.; Windel, H. (1956). "Über Einschlußverbindungen, X. Mitteil.: Die blauen Jodverbindungen der Cumarine und anderer verwandter Verbindungen". Chem. Ber. 89 (2): 354. doi:10.1002/cber.19560890227.

[1] Adams, R.; Mathieu, J. (1948). "A New Synthesis of Atranol (2,6-Dihydroxy-4-methylbenzaldehyde) and the Corresponding Cinnamic Acid". J. Amer. Chem. Soc. 70 (6): 2120. doi:10.1021/ja01186a037.

[2] Adams, R.; Bockstaheler, T.E. (1952). "Preparation and Reactions of o-Hydroxycinnamic Acids and Esters". J. Amer. Chem. Soc. 74 (21): 5346. doi:10.1021/ja01141a038.

[3] Cramer, F.; Windel, H. (1956). "Über Einschlußverbindungen, X. Mitteil.: Die blauen Jodverbindungen der Cumarine und anderer verwandter Verbindungen". Chem. Ber. 89 (2): 354. doi:10.1002/cber.19560890227.

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